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解沛忠
阅读次数: 添加时间:2020/07/02 发布:管理员

                                                                                           

解沛忠

E-mail: peizhongxie@njtech.edu.cn; peizhongxie0216@163.com

 

1. 教育和研究经历

2014.11-至今:南京工业大学 化学与分子工程学院

2013.7-2014.8東京大学(The University of Tokyo)理学部 博士后

合作导师:著名有机化学家Prof. Shū Kobayashi

2008.09- 2013.06 南开大学 元素有机化学国家重点实验室 有机化学/博士研究生,导师:黄有 教授,  陈茹玉 教授(院士)

 

2.科研工作

研究兴趣:绿色有机化学新反应探索及其机理研究;新型碱土金属催化体系设计以及在脱水偶联反应研究;以生物活性分子骨架为导向的绿色有机合成。

学术成果和研究项目:迄今,以第一/通讯作者在Nat. Commun.; Green Chem.; Org. Lett., Chem. Commun.; Chem. Eur. J.; Adv. Synth. Catal.等期刊发表论文20,申请中国发明专利5项。部分研究成果被Nat. Rev. Chem.专文亮点评述,被X-MOL,中国科技报等报道,入选ESI高被引论文。目前主持国家自然科学基金青年基金(21702108)和江苏省自然科学基金青年基金(BK20160977),获得江苏省“六大人才高峰”高层次人才资助。带领团队获得第四届江苏省科协青年会员创新创业大赛(化学化工领域)“一等奖”,晋级生命科学领域决赛并获得“三等奖”。

指导学生:指导的硕士研究生获得“国家奖学金”等奖励, 指导的本科生(郭磊)获得2017届江苏省优秀本科毕业论文“二等奖”等省部级奖励多项。

 

3. 发表论文:

  1. P. Xie*, Z. Sun, S. Li, X. Cai, J. Qiu, W. Fu, C. Gao, S. Wu, X. Yang, T.-P. Loh*, Reciprocal-activation strategy for allylic sulfination with unactivated allylic alcohols,
    Org. Lett. 2020, 22,
    4893.

  2. P. Xie*, Z. Sun, S. Li, L. Zhang, X. Cai, W. Fu, X. Yang, Y. Liu, X. Wo, T.-P. Loh*, Dehydrative cross-coupling of allylic alcohols with alkynes,
    Org. Lett. 2020, 22, 1599
    .

  3. P. Xie*, S. Li, Y. Liu, X. Cai, J. Wang, X. Yang, T.-P. Loh*, Alkaline-earth metal-catalyzed dehydrative allylic alkylation.
    Org. Lett. 2020, 22, 31
    .

  4. P. Xie*, X. Wo, X. Yang, X. Cai, S. Li, C. Gao, W. Fu, Z. Sun, T.-P. Loh*, Calcium-catalyzed regioselective dehydrative cross-coupling of propargylic alcohols with 1,3-dicarbonyl compounds,
    Green Chem. 2019,
    21, 5207.

  5. P. Xie*, W. Fu, X. Cai, Z. Sun, Y. Wu, S. Li, C. Gao, X. Yang, T.-P. Loh*, A Ba/Pd catalytic system enables dehydrative cross-coupling and excellent E-selective wittig reactions,
    Org. Lett. 2019,
    21, 7055.

  6. P. Xie*, W. Fu, Y. Wu, X. Cai, Z. Sun, S. Li, C. Gao, X. Yang, T.-P. Loh*, Allylic phosphorus ylides directly generated from alcohols with water as the only byproduct,
    Org. Lett. 2019, 21, 4168.

  7. P. Xie*, J. Wang, Y. Liu, J. Fan, X. Wo, W. Fu, Z. Sun, T.-P. Loh*, Water-promoted C-S bond formation reactions,
    Nat. Commun. 2018,
    9, 1321. (Highlighted by K. J. Geogheghan, Nat. Rev. Chem. 2018, 2, 3).

  8. Y. Liu, P. Xie*, Z. Sun, X. Wo, C. Gao, W. Fu, T.-P. Loh*, Direct substitution of secondary and tertiary alcohols to generate sulfones under catalyst and additive-free conditions,
    Org. Lett. 2018, 20, 5353.

  9. P. Xie*, J. Fan, Y. Liu, X. Wo, W. Fu, T.-P. Loh*, Bronsted acid/organic photoredox cooperative catalysis: Easy access to tri- and tetra-substituted alkenylphosphorus compounds from alcohols and P-H species,
    Org. Lett. 2018, 20, 3341.

  10. X. Wo, P. Xie*, W. Fu, C. Gao, Y. Liu, Z. Sun, T.-P. Loh*, Barium-catalyzed C-OH/P-H dehydrative cross-coupling for C-P Bond construction,
    Chem. Commun. 2018, 54, 11132.

  11. P. Xie*, J. Wang, J. Fan, Y. Liu, X. Wo, W. Fu, T.-P. Loh*, The C–OH/P–H dehydrative cross-coupling for the construction of the P–C bond under metal free conditions,
    Green Chem. 2017,
    19, 2135.

  12. P. Xie*, L. Guo, L. Xu, T.-P. Loh*, Asymmetric P-C bond formationdiastereoselective synthesis of adjacent P,C-stereogenic allylic phosphorus compounds,
    Chem. Asian J. 2016, 11, 1353.

  13. P. Xie, Y. Huang*, Morita-Baylis-Hillman adduct derivates (MBHADs): the versatile reactivity in Lewis base-promoted annulation,
    Org. Biomol. Chem. 2015, 13, 8578. (
    Review, ESI Highly Cited Paper)

  14. Y. Yamashita, Y. Cui, P. Xie, S. Kobayashi, Zinc Amide Catalyzed Regioselective Allenylation and Propargylation of Ketones with Allenyl Boronate,
    Org. Lett. 2015, 17, 6042,

  15. P. Xie, E. Li, J. Zheng, Y. Huang*, Sequential Catalyst Phosphine/Secondary Amine Promoted [1+4]/Rearrangement Domino Reaction for the Construction of (2H)-Pyrans and 2-Oxabicyclo[2.2.2]oct-5-ene Skeletons,
    Eur. J. Org. Chem. 2014, 1189.

  16. L. Liang, E. Li, P. Xie, Y. Huang,* Phosphine-Initiated Domino Reaction: A Convenient Method for the Preparation of Spirocyclopentanones,
    Chem. Asian J. 2014, 9, 1270.

  17. P. Xie, Y. Huang,* Cross-Rauhut-Currier Reactions Initiated Domino Annulations,
    Eur. J. Org. Chem. 2013, 6213. (
    Review, Invited by Editor)

  18. P. Xie, E. Li, J. Zheng, Y. Huang,* R. Chen, Tunable Phosphine-Mediated Domino Reaction: Selective Synthesis of 2,3-Dihydrofurans and Biaryls,
    Adv. Synth. Catal. 2013, 355, 161. (
    Hot Paper, Selected by Editor).

  19. E. Li, Y. Huang*, L. Liang, P. Xie, Phosphine-Catalyzed [4 + 2] Annulation of γ-Substituent Allenoates: Facile Access to Functionalized Spirocyclic Skeletons,
    Org. Lett. 2013, 15, 3138.

  20. E. Li, P. Xie, L. Yang, L. Liang, Y. Huang,* Tuning Catalysts to Tune the Products: Phosphine-Catalyzed Aza-Michael Addition Reaction of Hydrazones with Allenoates,
    Chem. Asian J. 2013, 8, 603.

  21. P. Xie, Y. Huang,* R. Chen, Phosphine-Mediated Domino Benzannulation Strategy for the Construction of Highly Functionalized Multiaryl Skeletons,
    Chem. Eur. J. 2012,18, 7362. (
    Most Accessed in May 2012, Top 10)

  22. P. Xie, W. Lai, Z. Geng, Y. Huang,* R. Chen, Phosphine-Catalyzed Domino Reaction for the Synthesis of Conjugated 2,3- Dihydrofurans from Allenoates and Nazarov Reagents,
    Chem. Asian J. 2012, 7, 1533.

  23. L. Yang, P. Xie, E. Li, X. Li, Y. Huang,* R. Chen, Phosphine-catalyzed domino reaction: an efficient method for the synthesis of highly functionalized spiro[furan-indoline]diones,
    Org. Biomol. Chem. 2012, 10, 7628.

  24. X. Meng, P. Xie, Y. Huang,* R. Chen, Organocatalytic domino reaction of salicyl N-thiophosphoryl imines and methyl vinyl ketone initiated by an aza-MBH reaction with bifunctional phosphine catalysts,
    RSC Adv. 2012, 2, 8104.

  25. P. Xie#, L. Wang#, L. Yang, E. Li, J. Ma, Y. Huang,* R. Chen, Domino Reaction for the Chemo- and Stereoselective Synthesis of trans-2,3-Dihydrobenzofurans from N-Thiophosphinyl Imines and Sulfur Ylides,
    J. Org. Chem. 2011,76, 7699. (#Equal contribution)

  26. P. Xie, Y. Huang,* W. Lai, X. Meng, Ruyu Chen, Bifunctional Phosphine -catalyzed cross-Rauhut–Currier/Michael/Aldol Condensation Triple Domino Reaction: Synthesis of Functionalized Cyclohexenes,
    Org. Biomol. Chem. 2011, 9, 6707.

  27. J. Ma, P. Xie, C. Hu, Y. Huang,* R. Chen, Substrate-Controlled, Phosphine-Catalyzed Domino Reactions of Activated Conjugated Dienes: Highly Diastereoselective Synthesis of Bicyclic Skeletons,
    Chem. Eur. J. 2011,17, 7418.

  28. P. Xie, Y. Huang,* R. Chen,* Phosphine-Catalyzed Domino Reaction: Highly Stereoselective Synthesis of trans-2,3-Dihydrobenzofurans from Salicyl N-Thiophosphinyl Imines and Allylic Carbonates,
    Org. Lett. 2010, 12, 3768-3771.

  29. X. Meng, Y. Huang*, H. Zhao, P. Xie, J. Ma, R. Chen, PPh3-Catalyzed Domino Reaction: A Facile Method for the Synthesis of Chroman Derivatives,
    Org. Lett. 2009, 11, 991.

 

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