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褚雪强、沈志良团队在Org. Lett.发表论文
阅读次数: 添加时间:2021/08/19 发布:

Nickel-Catalyzed Diastereoselective Reductive Cross-Coupling of Disubstituted Cycloalkyl Iodides with Aryl Iodides

Xuan-Di Song,a Meng-Meng Guo,a Shuang Xu,a Chuanji Shen,b Xiaocong Zhou,* b Xue-Qiang Chu,a Mengtao Ma,c and Zhi-Liang Shen*a

a Technical Institute of Fluorochemistry (TIF), Institute of Advanced Synthesis, School of Chemistry and Molecular Engineering, Nanjing Tech University, Nanjing 211816, China.

b College of Biological, Chemical Science and Engineering, Jiaxing University, 118 Jiahang Road, Jiaxing 314001, China

c College of Science, Nanjing Forestry University, Nanjing 210037, China

 

Abstract: A nickel-catalyzed direct reductive cross-coupling of disubstituted cycloalkyl iodides with aryl iodides was developed. The one-pot reaction, which is simple to operate, was capable of proceeding efficiently in a stereocontrolled manner to afford a variety of cross-coupled products with high diastereoselectivity and wide functional group tolerance.

 

Org. Lett. 2021, 23, 5118–5122 (Impact factor: 6.005)

论文链接:https://pubs.acs.org/doi/10.1021/acs.orglett.1c01649.

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