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解沛忠课题组在Org. Chem. Front.期刊上发表研究论文
阅读次数: 添加时间:2021/08/23 发布:

Practical allylation with unactivated allylic alcohols under mild conditions

Shuangshuang Lia, Ju Qiua, Bowen Lia, Zuolian Suna, Peizhong Xiea*, and Teck-Peng Lohab*

a School of Chemistry and Molecular Engineering, Nanjing Tech University, Nanjing 211816, P. R. China.

b Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, Singapore 637371.

Abstract: A practical palladium/calcium catalytic system was developed for dehydrative allylation concerning unactivated allylic alcohols. EtOH solvent with H2O additive was identified as powerful media to accelerate proton transfer. That catalytic system and environmentally benign media enabled a variety of soft carbonic nucleophiles and allylic alcohols reacted smoothly at room temperature with water as the only byproduct. A wide-spectrum of allylic compounds bearing a variety of functional groups can be obtained with high to excellent yields.

Org. Chem. Front. 2021, 8, 3354-3359.(影响因子:5.281

论文链接:https://pubs.rsc.org/en/content/articlepdf/2021/qo/d1qo00490e

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