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解沛忠课题组在Org. Lett.发表研究论文
阅读次数: 添加时间:2021/08/23 发布:

Dehydrative Allylation of Alkenyl sp2 C-H Bonds

Xinying Cai, Huicong Xing, Ju Qiu, Bowen Li, and Peizhong Xie*

School of Chemistry and Molecular Engineering, Nanjing Tech University, Nanjing 211816, P. R. China.

Abstract: We designed a cooperative catalytic system by combining commercially available Ca(NTf2)PF6 and Pd(PPh3)4 to address the dehydrative allylation of alkenyl sp2 C-H bonds in an environmentally benign manner. A novel C-OH bond cleavage method was found to be crucial for this practical protocol. A variety of alkenes and allylic alcohols equipped with wide-spectrum functional groups can be successfully incorporated into the desired cross-coupling, affording 1,4-dienes with moderate to excellent yields and high stereo- and regioselectivity.

Org. Lett. 2021, 23, 4368-4373.(影响因子:6.005

论文链接:https://pubs.acs.org/doi/10.1021/acs.orglett.1c01309

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