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何广科教授课题组在Org. Biomol. Chem.上发表研究论文
阅读次数: 添加时间:2021/11/01 发布:

PhI(OAc)2-Mediated Trifluoromethylthiolation/Oxidative Cyclization of Ynamides

Shixuan Su,a Zhipeng Yan,a Xingyuan Ye,a Jingyang Wangb, Yuan Lia and Guangke He*a


Abstract: A PhI(OAc)2-mediated trifluoromethylthiolation/oxidative cyclization of ynamides with Shen reagent has been established herein, providing a facile access to CF3S-substituted oxazolidine-2,4-diones bearing a quaternary carbon center in 38~85% yields with chemo-selectivities of up to 99/1.

Org. Biomol. Chem., 2021, 19, 8746–8753.

论文链接:https://pubs.rsc.org/en/content/articlelanding/2021/OB/D1OB01642C

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