工作单位：南京工业大学 化学与分子工程学院

办公地址：化学学科楼A303, B304

电子邮箱：ias_ydu@njtech.edu.cn

研究方向：

（1）面向锂离子电池应用的功能材料的合成和应用研究；

（2）推动新化学键构筑的功能催化剂的设计和应用研究；

（3）面向纳滤应用的共价框架膜的研制与性能探索。

主持及参与的项目：

（1）国家自然科学基金委员会, 联合基金项目, U24A2083, 高耐受性共价有机框架纳滤膜及组件的创制与药物高效分离应用, 2025-01 至 2028-12, 260万元, 在研, 参与

（2）中华人民共和国科学技术部, 国家重点研发计划, 2022YFB38052, 自具孔聚合物膜材料的多尺度设计及限域传质机制研究, 2022-11 至 2025-10, 1100万元, 在研, 参与

（3）膜材料与膜过程协同创新中心, 合作项目, 5060106302, 面向稀贵金属离子纳滤分离的共价有机框架的设计与合成, 2022-01 至 2024-12, 60万元, 结题, 主持

（4）南京工业大学, 国际合作培育项目, 3937300414, 二杂蒽有机共价框架高性能P/N型正极材料的联合研发, 2022-08 至 2023-07, 3万元, 结题, 主持

（5）江苏省科技厅 面上项目BK20191363，基于吩嗪及其类似物的新型有机共价框架正极材料的设计、合成与性能研究 2019-07-2022-06，10万元，结题，主持

（6）国家自然科学基金委，青年基金 21805134，基于9，10-二杂蒽的共价有机框架新型电极材料的设计、合成与性能研究，2019-01至2021-12，27万元，结题，主持

（7）南京市人社局、财政局优秀项目，基于9，10-二杂蒽的共价有机框架新型电极材料的设计、合成与性能研究，2018-09至2021-08，5万元，结题，主持

（8）南京工业大学科研启动39837141二杂蒽类COF的探索研究 2017.6-2020.12，60万元，结题，主持

学术论文（PEER-REVIEWED）：

1. Cui F, Zhang Y, Liu B, Jing Z and Du Y*, Phenoxazine-Based Covalent Organic Frameworks as a turn-off Fluorescent Probe for Trace Water Detection in Organic Solvents, Chem. Commun., 2025, 61, 4058-4061.

2. Ouyang B, Huang D, Bian X, Guo J, Peng X, Du Y and Yang H*, In Situ Electropolymerization of 2,7-di(thienyl)pyrene-4,5,9,10-tetraone for Superior Lithium-Ion Battery Cathodes, Chem. Eng. J., 2025, 161004.

3. Huang D, Ouyang B, Bian X, Guo J, Peng X, Du Y and Yang H, Hydrogen-Bonding Boosted Poly(Urea-Diaminoanthraquinone) As Superior Cathode Materials For Lithium-Ion Batteries, ACS Appl. Polym. Mater., 2025, 2890-2897.

4. Jing Z, Shi X, Tao X, Liu B, Yang H* and Du Y*, Flexible vs. Rigid Covalent Organic Frameworks: Catalytic Performance in the Knoevenagel Reaction, J. Mater. Chem. A, 2024, 12, 31818-31824.

5. Guo J, Peng X, Ouyang B, Huang D, Jing Z, Bian X, Du Y and Yang H*, Two P-type Ester-Linked Dihydrophenazine-Based Polymers as High-Performance Cathode Materials for Lithium-Ion Batteries, New J. Chem., 2024, 48, 11211-11215.

6. Peng X, Guo J, Huang D, Ouyang B, Du Y and Yang H, Progress In Pyrene-4,5,9,10-Tetraone-Based Organic Electrode Materials For Rechargeable Batteries, ChemSusChem, 2024, n/a, e202401975.

7. Lv S, He Q, Zhang Y, Guo J, Peng X, Du Y and Yang H, High Performance Cathode Materials For Lithium-Ion Batteries Based On A Phenothiazine-Based Covalent Triazine Framework, New Journal of Chemistry, 2023, 47, 10911-10915.

8. Jiang H, Mei H and Du Y*, An Oxidant-Free and Mild Approach to Fluorenones Via Direct Excitation of Aldehyde, Chem Catalysis, 2023, 3, 100581.

9. Liu L, Yin C, Li Y, Yang H, Du Y* and Wang Y*, Alkyl-Engineered Hydrophobic Channels in Covalent Organic Frameworks toward Fast Organic Solvent Nanofiltration, Ind. Eng. Chem. Res., 2023, 62, 21304-21310.

10. He Q, Lv S, Huang Y, Guo J, Peng X, Du Y and Yang H*, Dihydrophenazine-Derived Oligomers from Industrial Waste as Sustainable Superior Cathode Materials for Rechargeable Lithium-Ion Batteries, RSC Adv., 2023, 13, 12464-12468.

11. Wang Y, Huang Y, Hua Y, Du Y and Yang H*, Ultrastable Dihydrophenazine-Based Polymer from Industrial Waste as Sustainable Lithium-Ion Battery Cathode Material, New J. Chem., 2022, 46, 14314-14317.

12. Huang Y, Li Z, Hua Y, Wang Y, Wang B, Du Y and Yang H, Dihydrophenazine-Derived Redox Polymer From Industrial By-Product As Lithium-Ion Battery Cathode Material, ChemistrySelect, 2022, 7, e202200300.

13. Meng Z, Zhang Y, Dong M, Zhang Y, Cui F, Loh T-P, Jin Y, Zhang W*, Yang H* and Du Y*, Readily Usable Bulk Phenoxazine-Based Covalent Organic Framework Cathode Materials with Superior Kinetics and High Redox Potentials, J. Mater. Chem. A, 2021, 9, 10661-10665.

14. Wang H, Li Z, Meng Z, Guo X, Du Y* and Yang H*, An Easily Obtained Hypercrosslinked Pyrene-Based Porous Organic Polymer as a High Performance Electrode Material for Lithium-Ion Batteries, New J. Chem., 2021, 45, 7060-7064.

15. Hua Y, Huang Y, Wang Y, Du Y and Yang H*, Phenazine-Based Spiroborate Complex with Enhanced Electrochemical Stability for Lithium Storage, New J. Chem., 2021, 45, 21534-21537.

16. Guo X, Zhang Y, Chen H, Cui C, Li Z, Du Y*, Wang B* and Yang H*, Phenanthrenequinone-Based Linear Polymers as Sustainable Cathode Materials for Rechargeable Li-Ion Batteries, Int. J. Electrochem. Sci., 2020, 15, 7774-7787.

17. Zhang R, Zhang Y, Yin X, Meng Z, Du Y* and Yang H*, A High-Capacity Catechol-Based Cathode Material for Rechargeable Lithium-Ion Batteries, Int. J. Electrochem. Sci., 2020, 15, 8311-8320.

18. Zhang Y, Gao P, Guo X, Chen H, Zhang R, Du Y*, Wang B* and Yang H*, Hypercrosslinked Phenothiazine-Based Polymers as High Redox Potential Organic Cathode Materials for Lithium-Ion Batteries, RSC Adv., 2020, 10, 16732-16736.

授权专利：

1. 杜亚; 杨海申; 孟智颖; 张悦; 崔凤敏; 李震; 张瑛頔 ; 吩噁嗪二胺衍生物和/或吩噻嗪二胺衍生物及其制备方法, 2024-1-4, 中国, 202010483754.2

2. 杜亚; 张瑛頔; 李震 ; 吩噁嗪醛基衍生物及其制备方法与应用, 2023-11-14, 中国，202210234894.5

3. 杜亚; 李震; 谭晓宇 ; 基于三吡啶三甲醛基的二维共价有机框架材料及其制备方法与应用, 2023-9-15, 中国, 202210234633.3

4. 杜亚; 张悦; 张瑛頔; 刘玉婷 ; 吩噁嗪和吩噻嗪共价三嗪框架材料及其制备方法与应用, 2023-6-16, 中国, 202110550453.1

5. 杜亚; 崔凤敏; 张瑛頔; 李震 ; 咔唑三胺衍生物及其制备方法和应用, 2023-2-17, 中国, 202110549920.1

6. 杜亚; 张悦; 李震; 刘玉婷 ; 10-甲基吩噁嗪衍生物、其锆金属有机框架材料及制备方法, 2022-10-21, 中国, 202110549756.1

7. 杜亚; 崔凤敏; 李震; 谭晓宇; 陈江海 ; 吩噁嗪二维共价有机框架材料及其制备方法与应用, 2022-10-21, 中国, 202110549918.1

8. 杜亚; 崔超慧; 张瑛頔; 李震; 刘玉婷; 姜寒 ; 含羰基四苯基吡咯衍生物及其制备方法与应用, 2022-10-18, 中国, 202110549919.6

9. 杜亚; 杨海申; 孟智颖; 张赢; 董梦青; 崔超慧 ; 基于吩噁嗪的二维共价有机框架材料及其制备方法与应用, 2022-7-19, 中国, 202010483946.3

10. 杜亚; 崔超慧; 李震; 张瑛頔; 姜寒; 刘玉婷 ; 吡嗪二维有机多孔材料及其制备方法与应用, 2022- 7-19, 中国, 202110550452.7

11. 杜亚；杨海申；董梦青；孟智颖；双咪唑鎓盐钯负载多孔有机聚合物催化剂及其制法与应用，2023-9-19，中国 202010497603.2

Prior to NJTECH

1. Y. Du, H. Yang, J. Whiteley, S. Wan, S. Lee* and W. Zhang*, Ionic covalent organic frameworks with spiroborate linkage；Angew. Chem. Int. Ed., 2016, 55, 1737-1741.

2. Y. Du, Haishen Yang, Shun Wan, Yinghua Jin, Wei Zhang*, A titanium-based porous coordination polymer as a catalyst for chemical fixation of CO2, J. Mater. Chem. A., 2017, 5, 9163-9168.

3. Haishen Yang, Youlong Zhu, Y. Du, Dazhi Tan, Yinghua Jin  and  Wei Zhang, Aromatic-Rich Hydrocarbon Porous Networks through Alkyne Metathesis, Mater. Chem. Front., 2017, 2017, 1, 1369-1371.

4. Y. Du, Ryan M. Pearson, Chern-Hooi Lim, Steven M. Sartor, Matthew D. Ryan, Haishen Yang, Niels H. Damrauer, and Garret M. Miyake*, Strongly Reducing, Visible-Light Organic Photoredox Catalysts as Sustainable Alternatives to Precious Metals, Chem. Eur. J., 2017, 23, 10962;

5. Y. Du, H. Yang, C. Zhu, M. Ortiz, K. Okochi, R. Shoemaker, Y. Jin and W. Zhang*, Highly active multidentate triphenolmethine-based alkyne metathesis catalysts, Chem. Eur. J., 2016, 22, 7959-7963.

6. H. Yang, Y. Du, S. Wan, G. D. Trahan, Y. Jin, W. Zhang*, Mesoporous 2D covalent organic frameworks based on shape-persistent arylene-ethynylene macrocycles; Chem. Sci., 2015, 6, 4049-4053.

7. Q. Wang, C. Yu, H. Long, Y. Du, Y. Jin, and W. Zhang *, Solution phase dynamic assembly of permanently interlocked aryleneethynylene Cages through alkyne metathesis; Angew. Chem. Int. Ed., 2015, 127(26), 7550-7554.

8. Y. Du, T. K. Hyster, T. Rovis*, Rhodium(III)-catalyzed oxidative carbonylation of benzamides with carbon monoxide, Chem. Commun., 2011, 44, 12074-12076;

9. Y. Du, S. Oishi, S. Saito*, Selective N-alkylation of amines with alcohols by using non-metal-based acid-base cooperative catalysis，Chem. Eur. J., 2011, 17, 12262-12267;

10. Y. Du, Y. Wu, A.-H. Liu, L.-N. He*, Quaternary ammonium bromide functionalized polyethylene glycol: A highly efficient and recyclable catalyst for selective synthesis of 5-aryl-2-oxazolidinones from carbon dioxide and aziridines under solvent-free conditions, J. Org. Chem., 2008, 73 (12), 4709-4712;

11. Y. Du, D.-L. Kong, H.-Y. Wang, F. Cai, J.-S. Tian, J.-Q. Wang, L.-N. He*, Sn-catalyzed synthesis of propylene carbonate from propylene glycol and CO2 under supercritical conditions, J. Mol. Catal. A: Chem., 2005, 241, 233-237;

12. Y. Du, L.-N. He*, D.-L. Kong, Magnesium-catalyzed synthesis of organic carbonate from 1,2-diol/alcohol and carbon dioxide, Catal. Commun., 2008, 9(8), 1754-1758;

13. Y. Du, J.-Q. Wang, J.-Y. Chen, F. Cai, J.-S. Tian, D.-L. Kong, L.-N. He*, A poly(ethylene glycol)-supported quaternary ammonium salt for highly efficient and environmentally friendly chemical fixation of CO2 with epoxides under supercritical conditions, Tetrahedron Lett., 2006, 47(8), 1271-1275;

14. Y. Du, F. Cai, D.-L. Kong, L.-N. He*, Organic solvent-free process for the synthesis of propylene carbonate from supercritical carbon dioxide and propylene oxide catalyzed by insoluble ion exchange resins, Green Chem., 2005, 7, 518-523;

15. 何良年*, 杜亚, 王金泉, 二氧化碳的资源化利用及超临界二氧化碳中的化学反应,有机化学，2005, 25 (suppl 1), 157; )

16. H. Yang, Y. Jin, Y. Du, W, Zhang*, Application of alkyne metathesis in polymer synthesis, J. Mater. Chem. A, 2014, 2(17), 5986-5993;

17. 杜亚, 王金泉, 田杰生, 孔德林, 岳晓东, 何良年*, Organic reactions using gases in supercritical carbon dioxide,  精细化工中间体, 2005, 35(1), 1-7;

18. Y. Takada, A. Matsuoka, Y. Du, H. Naka, and S. Saito*, Acetals of N,N-dimethylformamides: Ambiphilic behavior in converting carbon dioxide to dialkyl carbonates, Chem. Lett., 2013, 42, 146-147;

19. K. Kakuma, Y. Yamazaki, Y.Du, Susumu Saito*, Synthesis of carbonates directly from 1 atm CO2 and alcohols using CH2Cl2,Tetrahedron, 2010, 66, 9675-9680;

20. Y. Wu, L.-N. He*, Y. Du, J.-Q.Wang, C.-X. Miao, W. Li*, Zirconyl chloride: an efficient recyclable catalyst for synthesis of 5-aryl-2-oxazolidinones from aziridines and CO2 under solvent-free conditions, Tetrahedron, 2009, 65, 6204-6210;

21. L.-N. He*, Y Du, C.-X. Miao, J.-Q. Wang, X.-Y. Dou, Y. Wu, Methodologies for chemical utilization of CO2 to valuable compounds through molecular activation by efficient catalysts, Frontiers of Chemical Engineering in China, 2009, 3, 224-228;

22. 汪靖伦, 何良年*, 王金泉, 杜亚, 苗成霞, 窦骁勇, 高健, Methodologies for chemical utilization of carbon dioxide, 精细化工中间体, 2009, 39(5), 1-7;

23. J.-S. Tian, F. Cai, J.-Q. Wang, Y. Du, L.-N. He*, Environmentally benign chemical conversion of CO2 into organic carbonates catalyzed by phosphonium salts, Phosphorus, Sulfur and Silicon and the Related Elements, 2008, 183, 494-498；

24. C.-X. Miao, J.-Q. Wang, Y. Wu, Y. Du, and L.-N. He*, Bifunctional metal-salen complexes as efficient catalysts for the fixation of CO2 with epoxides under solvent-free conditions, ChemSusChem., 2008, 1(3), 236-241;

25. X.-Y. Dou, J.-Q. Wang, Y. Du, E. Wang, L.-N. He*, Guanidinium salt functionalized PEG: an effective and recyclable homogeneous catalyst for the synthesis of cyclic carbonates from CO2 and epoxides under solvent-free conditions, Synlett, 2007, (19), 3058-3062;

26. J.-S. Tian, C.-X. Miao, J.-Q. Wang, F. Cai, Y. Du, Y. Zhao and L.-N. He*, Efficient synthesis of dimethyl carbonate from methanol, propylene oxide and CO2 catalyzed by recyclable inorganic base/phosphonium halide-functionalized polyethylene glycol, Green Chem., 2007, 9, 566-571;

27. L.-N. He*, J.-S. Tian, C.-X. Miao, F. Cai, J.-Q. Wang, Y. Du, Poly(ethylene glycol)-supported phosphonium halides in combination with inorganic bases/PEG for highly efficient synthesis of dimethyl carbonate from methanol, propylene oxide, and CO2, Preprints of Symposia - American Chemical Society, Division of Fuel Chemistry, 2006, 51, 534-535;

28. J.-S. Tian, J.-Q. Wang, Y. Du, L.-N. He*, Copolymerization of carbon dioxide with 1, 2-epoxides, Huaxue Jinzhan, 2006, 18(1), 74-79;

29. J.-Q. Wang, J.-S. Tian, Y. Du, L.-N. He*, Enzyme catalysis in supercritical carbon dioxide, Huaxue Tongbao, 2005, 68(8), w087(1-7);

30. X.-S. Wang*, D.-Q. Shi, Y. Du, Y. Zhou, and S.-J. Tu. Synthesis of 2-aminopyran derivatives and 3-arylpropionitrile derivatives catalyzed by KF/Al2O3, Synth. Commun. 2004, 34(8), 1425-1432.

书籍出版：

《绿色化学基本原理》 编写第七章 2018年出版

《二氧化碳化学》编写第十章 2013年出版