个人简历
2016至今 南京工业大学，先进化学制造研究院，教授
2012起 南洋理工大学，化学与生物化学系，研究员
2012年 南洋理工大学，有机化学，博士学位
2005年 毕业于南京理工大学并免试保送研究生
研究方向
主要从事有机氟化学及可见光氧化还原催化等领域的研究工作
学术成绩
冯超教授主要从事有机氟化学及可见光氧化还原催化等领域的研究工作，在选择性C-H键三氟甲基化，基于C-F/C-H键的偶联反应，自由基开环远程氟化反应，氟离子亲核加成诱导官能化，可见光促进的氟化双官能化，单电子氧化促进邻近官能团活化方面取得了一系列突出研究成果，在Chem, Journal of American Chemical Society, Angewandte Chemie International Edition, Nature Communications, Cell Reports Physical Science, Chemical Science, ACS Catalysis, Organic Letters, Chemical Communications等国际权威期刊以第一作者及通讯作者发表论文50余篇，申请发明专利10余件。2014年荣获Reaxys PhD Prize Finalist (该奖旨在奖励全世界在有机、金属有机及无机化学领域有突出原创性工作的博士生)，2016年入选国家高层次人才计划，2017年入选江苏省“特聘教授”，2018年入选江苏省“双创人才”，2021年入选江苏省“杰出青年”，承担国家自然科学基金面上项目(2018)、江苏省自然科学青年基金项目(2017)等。受邀在第十五、十六届全国有机氟化学会议、第十一届有机化学学术会议做邀请报告，并于2018年获Thieme Chemistry Journal Award。
代表性论文
1. Li, Xin;# Shui, Yang;# Shen, Pingkang; Wang, Yi-Peng; Zhang, Chi; Feng, Chao;* A novel type of radical-addition-induced β-fragmentation and ensuing remote functionalization. Chem DOI: 10.1016/j.chempr.2022.05.014. 2. Zhu, Chuan;# Zhang, Heng;# Liu, Qian; Chen, Kai; Liu, Ze-Yao; Feng, Chao;* Nickel-Catalyzed anti-Markovnikov Hydroalkylation of Trifluoromethylalkenes. ACS Catal. accepted. 3. Tang, Luning; Pei, Bing-Bing; Song, Yang; Xue, Fei; Yue, Yanni;* Feng, Chao;* Synthesis of Mono-fluoroallenes through Copper-Catalyzed Defluorinative Silylation of α,α-Difluoroalkylalkynes. Chin. J. Chem. 2022, 40, 2035-2039. 4. Liu, Haidong; Tian, Lifang; Wang, Hui; Li, Zhi-Qiang; Zhang, Chi; Xue, Fei; Feng, Chao;* A novel type of donor–acceptor cyclopropane with fluorine as the donor: (3 + 2)-cycloadditions with carbonyls. Chem. Sci. 2022, 13, 2686-2691. 5. Sun, Meng-Meng; Liu, Haidong; Zhu, Chuan;* Feng, Chao;* SN2′ Defluorinative Allylation of Trifluoromethylalkenes with Allylsilanes. Synthesis, 2022, 50, 1108-1114. 6. Zhang, Xing-Gui; Li, Xin; Zhang, Chi; Feng, Chao;* Multisubstituted Cyclohexene Construction through Telescoped Radical-Addition Induced Remote Functional Group Migration and Horner−Wadsworth−Emmons (HWE) Olefination. Org. Lett. 2021, 23, 9611-9615. 7. Tang, Hai-Jun; Zhang, Bin; Xue, Fei; Feng, Chao;* Visible-Light-Induced Meerwein Fluoroarylation of Styrenes, Org. Lett. 2021, 23, 4040-4044. 8. Wang, Cheng-Qiang;# Li, Yi;# Feng, Chao;* Sterically congested boronate and silane synthesis via electronically controlled protoboration and protosilylation, Cell Reports Physical Science 2021, 2, 100461. 9. Zhu, Chuan;# Sun, Meng-Meng;# Chen, Kai; Liu, Haidong; Feng, Chao;* Angew. Chem. Int. Ed. 2021, 60, 20237-20242. 10. Wang, Ding-Xing; Cai, Sai-Hu; Liu, Haidong; Ye, Lu; Zhu, Chuan;* Feng, Chao;* Visible-Light-Induced Iminothiolation of Unactivated Alkenes, Asian J. Org. Chem. 2021, 10, 1386-1389. 11. Liu, Haidong; Li, Yi; Wang, Ding-Xing; Sun, Meng-Meng; Feng, Chao;* Visible-Light-Promoted Regioselective 1,3-Fluoroallylation of gem-Difluorocyclopropanes, Org. Lett. 2020, 22, 8681-8686. 12. Zhu, Chuan;# Liu, Ze-Yao;# Tang, Luning; Zhang, Heng; Zhang, Yu-Feng; Walsh, Patrick J.;* Feng, Chao;* Migratory functionalization of unactivated alkyl bromides for construction of all-carbon quaternary centers via transposed tert-C-radicals, Nat. Commun. 2020, 11, 4860. 13. Che, Yuan-Yuan;# Yue, Yanni;# Lin, Ling-Zhi; Pei, Bingbing; Deng, Xuezu; Feng, Chao;* Palladium‐Catalyzed Electrophilic Functionalization of Pyridine Derivatives through Phosphonium Salts, Angew. Chem. Int. Ed. 2020, 59, 16414-16419. 14. Tang, Hai-Jun; Zhang, Xinggui; Zhang, Yu-Feng; Feng, Chao;* Visible-Light-Assisted Gold-Catalyzed Fluoroarylation of Allenoates, Angew. Chem. Int. Ed. 2020, 59, 5242-5247. 15. Ge, Liang; Wang, Ding-Xing; Xing, Renyi; Ma, Di; Walsh, Patrick J.;* Chao, Feng;* Photoredox-catalyzed oxo-amination of aryl cyclopropanes, Nat. Commun. 2019, 10, 4367-4375. 16. Lin, Ling-Zhi; Che, Yuan-Yuan; Bai, Peng-Bo; Feng, Chao;* Sulfinate-Engaged Nucleophilic Addition Induced Allylic Alkylation of Allenoates, Org. Lett. 2019, 21, 7424-7429. 17. Liu, Haidong; Ge, Liang; Wang, Ding-Xing; Chen, Nan; Feng, Chao;* Photoredox-Coupled F-Nucleophilic Addition: Allylation of gem-Difluoroalkenes, Angew. Chem. Int. Ed. 2019, 58, 3918-3922. 18. Song, Shengjin; Liu, Huan; Wang, Lu; Zhu, Chuan; Loh, Teck-Peng;* Feng, Chao;* Rhodium-Catalyzed Defluorinative Vinylation of gem-Difluoroalkenes for the Synthesis of 2-Fluoro-1,3-dienes, Chin. J. Chem. 2019, 37, 1036-1040. 19. Zhu, Chuan;# Zhang, Yu-Feng;# Liu, Ze-Yao; Zhou, Lu; Liu, Haidong; Feng, Chao;* Selective C–F Bond Carboxylation of gem-Difluoroalkenes with CO2 by photoredox/palladium dual catalysis, Chem. Sci. 2019, 10, 6721-6726. 20. Tang, Luning; Liu, Ze-Yao; She, Wenzhi; Feng, Chao;* Selective Single C–F Bond Arylation of Trifluoromethylalkene Derivatives, Chem. Sci. 2019, 10, 8701-8705. 21. Wang, Lu; Lu, Chengrong; Yue, Yanni;* Feng, Chao;* Visible-Light-Promoted Oxo-Sulfonylation of Ynamides with Sulfonic Acids, Org. Lett. 2019, 21, 3514-3517. 22. Zhou, Lu;# Zhu, Chuan;# Bi, Peijia; Feng, Chao;* Ni-catalyzed migratory fluoro-alkenylation of unactivated alkyl bromides with gemdifluoroalkenes, Chem. Sci. 2019, 10, 1144-1149. 23. Zhang, Yu; Liu, Haidong; Tang, Luning; Tang, Hai-Jun; Wang, Lu; Zhu, Chuan; Feng, Chao;* Intermolecular Carboamination of Unactivated Alkenes, J. Am. Chem. Soc. 2018, 140, 10695-10699. 24. Cai, Sai-Hu; Wang, Ding-Xing; Ye, Lu; Liu, Ze-Yao; Feng, Chao;* Loh, Teck-Peng;* Pyrroline Synthesis via Visible-Light-Promoted Hydroimination of Unactivated Alkenes with N,N’-Dimethylpropylene Urea as H-Donor. Adv. Synth. Catal. 2018, 360, 1262-1266. 25. Tang, Hai-Jun; Zhang, Yu-Feng; Jiang, Yi-Wen; Feng, Chao;* F– Nucleophilic-Addition-Induced [3 + 2] Annulation: Direct Access to CF3-Substituted Indenes, Org. Lett. 2018, 20, 5190-5193. 26. Zhou, Lu;# Zhu, Chuan;# Loh, Teck-Peng;* Feng, Chao;* Rh-Catalyzed C–H bond alkylation of indoles with α,α-difluorovinyl tosylate via indolyl group migration, Chem. Commun. 2018, 54, 5618-5621. 27. Zhu, Chuan; Wang, Cheng-Qiang; Feng, Chao;* Recent advance in transition-metal-catalyzed oxidant-free 4+1 annulation through C–H bond activation, Tetrahedron Lett. 2018, 59, 430-437. 28. Wang, Cheng-Qiang; Ye, Lu; Loh, Teck-Peng,* Feng, Chao,* C-F Bond Cleavage Enabled Redox-Neutral [4+1] Annulation via C-H Bond Activation, J. Am. Chem. Soc. 2017, 139, 1762-1765. 29. Wang, Cheng-Qiang; Zhang, Yu; Feng, Chao,* Fluorine Effects on Group Migration via a Rhodium(V) Nitrenoid Intermediate, Angew. Chem. Int. Ed. 2017, 56, 14918-14922. 30. Tang, Hai-Jun; Lin, Ling-Zhi; Feng, Chao;* Loh, Teck-Peng,* Palladium-Catalyzed Fluoroarylation of gem-Difluoroalkenes, Angew. Chem. Int. Ed. 2017, 56, 9872-9876. 31. Liu, Huan;# Song, Shengjin;# Wang, Cheng-Qiang; Feng, Chao;* Loh, Teck-Peng;* Redox-Neutral Rhodium-Catalyzed [4+1] Annulation via Formal Dehudrogenative Vinylidene insertion, ChemSusChem 2017, 10, 58-61. 32. Ye, Lu; Cai, Sai-Hu; Wang, Ding-Xing; Wang, Yi-Qiu; Lai, Lin-Jie; Feng, Chao;* Loh, Teck-Peng;* Org. Lett. 2017, 19, 6164-6167. 33. Zhu, Chuan;# Song, Shengjin;# Zhou, Lu; Wang, Ding-Xing; Feng, Chao;* Loh, Teck-Peng;* Nonconventional difluoroalkylation of C(sp2)–H bonds through hydroarylation, Chem. Commun. 2017, 53, 9482-9485. 34. Cai, Sai-Hu; Ye, Lu; Wang, Ding-Xing; Wang, Yi-Qiu; Lai, Lin-Jie; Zhu, Chuan; Feng, Chao;* Loh, Teck-Peng;* Chem. Commun. 2017, 53, 8731-8734. 35. Zhu, Chuan; Feng, Chao;* Motoki Yamane;* Pd/Cu cooperative catalysis: an efficient synthesis of (3-isoindazolyl)allenes via cross-coupling of 2-alkynyl azobenzenes and terminal alkynes, Chem. Commun. 2017, 53, 2606-2609. 36. Song, Shengjin; Lu, Ping; Liu, Huan; Cai, Sai-Hu; Feng, Chao;* Loh, Teck-Peng;* Switchable C-H Functionalization of N Tosyl Acrylamides with Acryloylsilanes, Org. Lett. 2017, 19, 2869-2872. 37. Tian, Panpan;# Wang, Cheng-Qiang;# Cai, Sai-Hu; Song, Shengjin; Ye, Lu; Feng, Chao;* Loh, Teck-Peng,* F- Nucleophilic-Addition-Induced Allylic Alkylation, J. Am. Chem. Soc. 2016, 138, 15869-15872. 38. Wang, Cheng-Qiang; Feng, Chao;* Loh, Teck-Peng;* Rh(III)-Catalyzed hydroarylation of Internal Alkynes Through C-H Bond Activation, Asian, J. Org. Chem. 2016, 5, 1002-1007. 39. Ren, Shichao;# Song, Shengjin;# Ye, Lu; Feng, Chao;* Loh, Teck-Peng;* Copper-catalyzed oxyamination of electron-deficient alkenes with N-acyloxyamines, Chem. Commun. 2016, 52, 10373-10376. 40. Cai, Sai-Hu; Xie, Jia-Hao; Ye, Lu; Feng, Chao;* Loh, Teck-Peng;* Visible-Light-Promoted Carboimination of Unactivated Alkenes for the Synthesis of Densely Functionalized Pyrroline Derivatives, ACS Catal. 2016, 6, 5571-5574. 41. Tian, Panpan; Feng, Chao;* Loh, Teck-Peng;* Rhodium-catalysed C(sp2)-C(sp2) bond formation via C-H/C-F activation, Nat. Commun. 2015, 6, 7472-7478. 42. Lu, Ping; Feng, Chao;* Loh, Teck-Peng;* Divergent Functionalization of Indoles with Acryloyl Silanes via Rhodium-Catalyzed C-H Activation, Org. Lett. 2015, 17, 3210-3213. 43. Ren, Shichao; Feng, Chao;* Loh, Teck-Peng;* Iron- or silver-catalyzed oxidative fluorination of cyclopropanols for the synthesis of β-fluoroketones, Org. Biomol. Chem. 2015, 13, 5105-5109. 44. Feng, Chao;# Feng, Daming;# Loh, Teck-Peng;* Rhodium(III)-catalyzed C–H allylation of electron-deficient alkenes with allyl acetates, Chem. Commun. 2015, 51, 342-345. 45. Yang, Xiao-Fei; Hu, Xu-Hong; Feng, Chao;* Loh, Teck-Peng;* Rhodium(III)-catalyzed C7-position C–H alkenylation and alkynylation of indolines, Chem. Commun. 2015, 51, 2532-2535. 46. Feng, Chao; Loh, Teck-Peng;* Rhodium-Catalyzed C-H Alkynylation of Arenes at Room Temperature, Angew. Chem. Int. Ed. 2014, 53, 2722-2726. 47. Feng, Chao; Feng, Daming; Luo, Yang; Loh, Teck-Peng;* Rhodium(III)-Catalyzed Olefinic C-H Alkynylation of Acrylamides Using Tosyl-Imide as Directing Group, Org. Lett. 2014, 16, 5956-5959. 48. Feng, Chao;# Feng, Daming;# Loh, Teck-Peng;* Rhodium(III)-catalyzed olefinic C–H alkynylation of enamides at room temperature, Chem. Commun. 2014, 50, 9865-9868. 49. Feng, Chao; Loh, Teck-Peng;* Rhodium(III)-Catalyzed Cross-Coupling of Alkenylboronic Acids and N-Pivaloyloxylamides, Org. Lett. 2014, 16, 3444-3447. 50. Feng, Chao; Loh, Teck-Peng;* Directing Group Assisted Copper-Catalyzed Olefinic Trifluoromethylation of Electron-Deficient Alkenes, Angew. Chem. Int. Ed. 2013, 12414-12417. 51. Feng, Chao;# Feng, Daming;# Loh, Teck-Peng;* Oxidant-Free Rh(III)-Catalyzed Direct C–H Olefination of Arenes with Allyl Acetates, Org. Lett. 2013, 15, 3670-3673. 52. Feng, Chao; Loh, Teck-Peng;* Copper-catalyzed olefinic trifluoromethylation of enamides at room temperature, Chem. Sci. 2012, 3, 3458-3462. 53. Feng, Chao; Loh, Teck-Peng;* Rhodium-catalyzed direct ortho C–H olefination of phenol derivatives, Chem. Commun. 2011, 47, 10458-10460. 54. Feng, Chao; Loh, Teck-Peng;* Palladium-catalyzed bisolefination of C-C triple bonds: a facile method for the synthesis of naphthalene derivatives, J. Am. Chem. Soc. 2010, 132, 17710-17712. 55. Feng, Chao; Loh, Teck-Peng;* Palladium-catalyzed decarboxylative cross-coupling of alkynyl carboxylic acids with arylboronic acids, Chem. Commun. 2010, 46, 4779-4781.
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冯超 教授 Email:iamcfeng@njtech.edu.cn |
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