赵恺 教授
Email: ias_kzhao@njtech.edu.cn
个人简介：
2022-至今 南京工业大学, 化学与分子工程学院, 教授
2017-2022 南京工业大学, 先进化学制造研究院, 副教授
2015-2016 新加坡南洋理工大学, 化学与生物化学系, 博士后 (导师: Teck-Peng Loh教授)
2014-2015 新加坡南洋理工大学, 化学与生物化学系, 研究助理
2010-2014 新加坡南洋理工大学, 化学与生物化学系, 博士 (导师: Teck-Peng Loh教授)
2007-2010 苏州大学, 材料与化学化工学部, 硕士 (导师: 纪顺俊教授)
2003-2007 苏州大学, 材料与化学化工学部, 学士
学术成绩：
主要从事烯酰胺类化合物的区域及立体选择性碳-氢官能化转化，廉价过渡金属催化的碳-碳成键反应，光催化的环境友好型自由基反应等领域的研究工作。自2017年9月入职南京工业大学以来，已累计发表高质量SCI论文 (影响因子>5.0) 13篇，影响因子总和突破140; 累计被引180余次。其中以第一作者身份在Chemical Society Reviews (影响因子: 54.564)发表封面论文1篇 (Chem. Soc. Rev. 2017, 46, 586.)；以通讯作者身份在Chemical Science (影响因子: 9.825) 上发表论文1篇 (Chem. Sci. 2019, 10, 8792.)并被知名公众号X-Mol重点评述；在Green Chemistry (影响因子: 11.034)上发表论文3篇 (Green Chem. 2022, 24, 4004; Green Chem. 2022, 24, 6524; Green. Chem. 2020, 22, 5497.)；在Organic Letters (影响因子：6.555)上发表论文4篇 (Org. Lett. 2020, 22, 9029; Org. Lett. 2019, 21, 5101; Org. Lett. 2019, 21, 6155; Org. Lett. 2019, 21, 8395.)；在Organic Chemistry Frontiers (影响因子: 5.456)上发表论文3篇 (Org. Chem. Front. 2022, 9, 6540; Org. Chem. Front. 2021, 8, 4086; Org. Chem. Front. 2019, 6, 94.)，相继入选该杂志热点论文，并被公众号Frontiers Journals重点评述；在Advanced Synthesis & Catalysis (影响因子: 5.837)上发表论文1篇 (Adv. Synth. Catal. 2019, 361, 3593.)。
所获奖励及荣誉：
1. 江苏省双创博士 (2018)
2. 第三届江苏省教师教学创新大赛特等奖 (2023)
3. 第五届江苏省科协青年会员(化学化工领域)创新创业大赛一等奖 (2020)
4. 第七届江苏省科协青年会员(化学化工领域)创新创业大赛二等奖 (2022)
5. 第三届南京工业大学教师教学创新大赛特等奖 (2022)
6. 第十二届南京工业大学“明发杯”青年教师授课竞赛特等奖 (2022)
7. 第二届南京工业大学教师教学创新大赛一等奖 (2021)
8. 第十一届南京工业大学“明发杯”青年教师授课竞赛一等奖 (2020)
9. 南京工业大学“以誓立廉，以行践廉”誓词征集最佳创意作品奖 (2022)
10. 南京工业大学微课教学比赛二等奖 (2022)
11. 南京工业大学实验创新大赛三等奖 (2022)
代表性论文：
1. Guan, T.; Guo, J.-Y.; Zhang, Q.-H.; Xu, X.-W.; Yu, X.-Y.; Zhang, Y.; Zhao, K.* Photoredox-Catalyzed Regio- & Stereoselective C(sp2)–H Cyanoalkylation of Enamides with Cycloketone Oximes via Selective C–C Bond Cleavage/Radical Addition Cascade. Green Chem. 2022, 24, 6524−6530. (SCI一区；IF: 11.034)
2. Tao, J.-Y.; Wang, Y.-X.; Zhang, Q.-H.; Ni, K.; Zhu, T.-H.; Zhao, K.* Transition-Metal-Free Regioselective and Stereoselective C(sp2)-C(sp3) Coupling of Enamides with Ethers or Alkanes via Photoredox-Catalyzed Cross-Dehydrogenative Coupling Reactions. Green Chem. 2022, 24, 4004−4011. (SCI一区；IF: 11.034)
3. Zhao, K.*; Zhang, X.-C.; Tao, J-Y.; Wu, X.-D.; Wu, J.-X.; Li, W.-M.; Zhu, T.-H.*; Loh, T.-P.* Regio- and Stereoselective C(sp2)-H Acylation of Enamides with Aldehydes via Transition- Metal Free Photoredox Catalysis. Green Chem. 2020, 22, 5497−5503. (SCI一区；IF: 10.182)
4. Zhao, K.; Shen, L.; Shen, Z.-L.*; Loh, T.-P.*Transition Metal-Catalyzed Cross-Coupling Reactions Using Organoindium Reagents, Chem. Soc. Rev. 2017, 46, 586−602. (SCI一区；IF: 54.564)
5. Guo, J.-Y.; Zhang, Z.-Y.; Guan, T.; Mao, L.-W.; Ban, Q.; Zhao, K.*; Loh, T.-P.* Photoredox-Catalyzed Stereoselective Alkylation of Enamides with N-Hydroxyphthalimide Esters via Decarboxylative Cross-Coupling Reactions. Chem. Sci. 2019, 10, 8792−8798. (SCI一区；IF: 9.825)
6. Zhao, K.*; Zhang, Z.-Y.; Cui, X.-L.; Wang, Y.-X.; Wu, X.-D.; Li, W.-M.; Wu, J.-X.; Zhao, L.-L.*; Guo, J.-Y.*; Loh, T.-P.* Visible-Light-Induced Regio- and Stereoselective C(sp2)−H Trifluoroethylation of Enamides with 2,2,2-Trifluoroethyl Iodide. Org. Lett. 2020, 22, 9029−9035. (SCI一区；IF: 6.091)
7. Guo, J.-Y.; Guan, T.; Tao, J.-Y.; Zhao, K.*; Loh, T.-P.* Stereoselective C(sp2)-H Alkylation of Enamides with Unactivated Aliphatic Carboxylic Acids via Decarboxylative Cross-Coupling Reactions, Org. Lett. 2019, 21, 8395−8399. (SCI一区；IF: 6.555)
8. Zhu, T.-H.; Zhang, Z.-Y.; Tao, J.-Y.; Zhao, K.*; Loh, T.-P.* Regioselective and Stereoselective Difluoromethylation of Enamides with Difluoromethyltriphenyl-phosphonium Bromide via Photoredox Catalysis, Org. Lett. 2019, 21, 6155−6159. (SCI一区；IF: 6.555)
9. Zhang, Y.-H.; Zhang, W.-W.; Zhang, Z.-Y.; Zhao, K.*; Loh, T.-P.* Manganese-Catalyzed Ring-Opening Coupling Reactions of Cyclopropanols with Enones, Org. Lett. 2019, 21, 5101−5105. (SCI一区；IF: 6.555)
10. Tao, J.-Y.; Zhang, Q.-H.; Zhu, T.-H.; Xu, X.-W.; Ni, K.; Zhao, Q.; Qin, Z.-B.; Zhang, Y.; Zhao, L.; Zhao, K.* Visible-Light-Initiated Regio and Stereoselective C(sp2)–H Phosphorylation of Enamides under Transition-Metal-Free Conditions. Org. Chem. Front. 2022, 9, 6540−6546. (SCI一区；IF: 5.456)
11. Zhao, K.*; Guo, J.-Y.*; Guan, T.; Wang, Y.-X.; Tao, J.-Y.; Zhang, Y.; Zhang, Q.-H.; Ni, K.; Loh, T.-P.* Photoinitiated Stereoselective Direct C(sp2)-H Perfluoroalkylation and Difluoroacetylation of Enamides. Org. Chem. Front. 2021, 8, 4086−4094. (SCI一区；IF: 5.456)
12. Zhu, T.-H.; Zhang, X.-C.; Zhao, K.*; Loh, T.-P.* Cu(OTf)2-Mediated C(sp2)-H Arylsulfonylation of Enamides via the Insertion of Sulfur Dioxide, Org. Chem. Front. 2019, 6, 94−98. (SCI一区；IF: 5.076)
13. Zhu, T.-H.; Zhang, X.-C.; Zhao, K.*, Loh, T.-P.* Direct C(sp2)−H Arylsulfonylation of Enamides via iridium(III)-Catalyzed Insertion of Sulfur Dioxide with Aryldiazonium Tetrafluoroborates. Adv. Syn. & Catal. 2019, 361, 3593−3598. (SCI二区；IF: 5.837)
14. Zhao, K.; Loh, T.-P.*, Asymmetric Conjugate Addition of Grignard Reagents to 3-silyl Unsaturated Esters for the Facile Preparation of Enantioenriched β-Silylcarbonyl Compounds and Allylic Silanes, Chem. Eur. J. 2014, 20, 16764−16772.
15. Zhao, K.; Zhu, S.-L.; Shi, D.-Q.; Xu, X.-P.*; Ji, S.-J.*, Regioselective Synthesis of Highly Functionalized 3-Spiropyrrolidine/pyrrolizidine Oxindoles and Acenaphthenones via One-Pot Four-Component [3+2] Cycloaddition, Synthesis 2010, 1793−1803.
16. Zhao, K.; Xu, X.-P.; Zhu, S.-L.; Shi, D.-Q.; Zhang, Y.; Ji, S.-J.*, Facile and Efficient Synthesis of a New Class of Indole-Substituted Pyridine Derivatives via One-Pot Multicomponent Reactions, Synthesis 2009, 2697−2708.
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