THE LEWIS BONDING MODEL AND BEYOND

报 告 人：Professor Gernot Frenking

报告时间：2016年12月15日（星期四）上午9:00

报告地点：南京工业大学丁家桥校区科技创新大楼C501

报告摘要：The lecture discusses fundamental questions of chemical bonding in the light of the Lewis electron-pair model which was introduced 100 years ago [1]. Topics include the electronic structure of molecules with unusual bonds [2] and the differences of chemical bonding between atoms of the first octal row and heavier homologues [3]. It is shown that the complementary model of electron-sharing bonds A-B and dative bonds A→B is very useful to explain molecular structures and to predict novel compounds [4].

参考资料：

[1] a) G.N. Lewis, J. Am. Chem. Soc. 1916, 38, 762. b) A. Krapp, F. M. Bickelhaupt, G. Frenking, Chem. Eur. J. 2006, 12, 9196.

[2] a) G. Frenking, R. Tonner, S. Klein, N. Takagi, T. Shimizu, A. Krapp, K. K. Pandey, P. Parameswaran, Chem. Soc. Rev. 2014, 43, 5106. b) J. Jin, G. Wang, M. Zhou, D. M. Andrada, M. Hermann, G. Frenking, Angew. Chem. Int. Ed. 2016, 55, 2078. c) K. C. Mondal, S. Roy, B. Dittrich, D. M. Andrada, G. Frenking, H. W. Roesky, Angew. Chem. Int. Ed. 2016, 55, 3158. d) Z.-H. Cui, W-S. Yang, L. Zhao, Y.-H. Ding, G. Frenking, Angew. Chem. Int. Ed., 2016, 55, 7841. e) C. Mohapatra, S. Kundu, A. N. Paesch, R. Herbst-Irmer, D. Stalke, D. M. Andrada, G. Frenking, H. W. Roesky, J. Am. Chem. Soc. 2016, 138, 10429.

[3] a) P. Jerabek, G. Frenking, Theoret. Chem. Acc. 2014, 133, 1447. b) G. Frenking, in 'The Chemical Bond. Chemical Bonding Across the Periodic Table’, p. 25-48, G. Frenking and S. Shaik (Eds), Wiley-VCH, Weinheim, 2014. c) M. Lein, A. Krapp, G. Frenking J. Am. Chem. Soc. 2005, 127, 6290.

[4] a) G. Frenking, Angew. Chem. Int. Ed. 2014, 53, 6040. b) M. Hermann, G. Frenking, Structure and Bonding 2016, 169, 131. c) G. Frenking, M. Hermann, D.M. Andrada, N. Holzmann, Chem. Soc. Rev. 2016, 45, 1129.

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